羟基氧化铁-藻酸钙复合珠连续流吸附除砷研究
Study on Arsenic Removal by Continuous-Flow Adsorption Using Iron Oxyhydroxide-Calcium Alginate Composite Beads
摘要 在筛选出优势除砷吸附剂羟基氧化铁(HFO)的基础上,通过包埋制得羟基氧化铁-藻酸钙复合珠(IACB).在影响因素实验、动力学以及热力学实验的基础上,开展连续流实验预测As穿透曲线,探究材料的动态吸附容量,并通过数学模型拟合分析动态吸附动力学.在1.5、2.0、2.5 mL/min三种不同的进水流速下,Thomas模型预测IACB对矿井水中砷的平衡动态吸附容量分别为13.876、15.810、12.712 mg/g,Yoon-Nelson模型预测50%穿透点对应的时间分别为91、78、67 d,Adams-Bohart模型拟合结果表明,吸附的速率与吸附剂剩余容量以及被吸附物浓度之间并非呈正比关系.进一步通过表征分析揭示了连续流实验中IACB与矿井水中砷的反应机理.研究表明,IACB的静态或连续流吸附效果优于活性氧化铝、改性海泡石、改性活性炭等材料,不仅解决了HFO应用的缺陷,而且具备动态吸附容量高和长效使用的优势,在矿井水砷污染治理领域具有良好的应用前景.
Abstract:
Based on the screening of hydroxyiron oxide(HFO)as a superior arsenic-removing adsorbent,iron oxyhydroxide-calcium alginate composite beads(IACB)were prepared via embedding.On the basis of influence factor experiments,kinetic experiments,and thermodynamic experiments,continuous flow experiments were conducted to predict the As breakthrough curve,explore the dynamic adsorption capacity of the material,and analyze the dynamic adsorption kinetics through mathematical model fitting.Under three different influent flow rates(1.5,2.0,and 2.5 mL/min),the Thomas model predicted that the equilibrium dynamic adsorption capacities of IACB for arsenic in mine water were 13.876,15.810,and 12.712 mg/g,respectively.The Yoon-Nelson model predicted that the times corresponding to the 50%breakthrough point were 91,78,and 67 days,respectively.The fitting results of the Adams-Bohart model indicated that the adsorption removal rate was not proportional to the remaining capacity of the adsorbent and the concentration of the adsorbate.Furthermore,the reaction mechanism between IACB and arsenic in mine water during the continuous flow experiments was revealed through characterization analysis.Studies demonstrated that the static or continuous flow adsorption performance of IACB was superior to that of materials such as activated alumina,modified sepiolite,and modified activated carbon.IACB not only solves the defects of HFO in practical application but also possesses the advantages of high dynamic adsorption capacity and long-term service life,thereby exhibiting good application prospects in the field of mine water arsenic pollution control.
刊 名 水处理技术 ISTICPKU
年,卷(期): 2026, 52(9)
分类号: X703
机标分类号: X703 TQ424.2 TP311.52
在线出版日期: 2026年10月12日
基金项目: 2023YFC3709902:国家重点研发计划2024JC-YBMS-230:陕西省自然科学基础研究计划面上项目42307113:国家自然科学基金,